Under the watchful eye of new sporting director Leonardo, Paris fell behind to an early Óscar Cardozo goal, but equalized soon after when Clément Chantôme's cushioned through ball was brilliantly lobbed home by Nenê.
However, in this rematch of last season's Europa League tie, which Benfica won on aggregate, Franco Jara and Javier Saviola both netted after the restart to give the Lisbon club the win once again.
[7] PSG recorded their first pre-season win, beating English second tier club Brighton & Hove Albion with Nenê making the difference, his goal laid on a plate by new signing Kevin Gameiro.
[11] Alexandre Pato's fourth-minute goal meant Carlo Ancelotti's reign at PSG started with a loss as Milan beat the capital club in the Dubai Challenge Cup at the Al-Rashid Stadium.
[19] Paris Saint-Germain were ominously impressive against Montpellier, Javier Pastore scoring twice and Kevin Gameiro once to win at the Stade de la Mosson.
[20] A sublime strike from Javier Pastore – and a late volley from Christophe Jallet – won PSG a thrilling victory over closest rivals Lyon, taking the capital club three points clear atop the table.
[26] Marseille took the clasico honours to condemn Paris Saint-Germain to a second straight league defeat, leaving Montpellier three points clear at the top.
[31] Nenê scored twice and Javier Pastore netted his first league goal since October as leaders PSG beat Toulouse at the Parc des Princes to give Carlo Ancelotti the perfect start to his Ligue 1 coaching career.
[33] Paris Saint-Germain maintained their winning run under Carlo Ancelotti after strikes from Nenê and Kevin Gameiro brought the Parisians back from a goal down to beat Evian at the Parc des Princes.
[34] Carlo Ancelotti's perfect start as coach of Paris Saint-Germain ended after the capital club were held to a goalless draw by an impressive Nice.
[36] Guillaume Hoarau salvaged a draw for Paris Saint-Germain at Lyon in Ligue 1's match of the season with a 94th-minute equalizer as the capital club slipped from top spot.
[48] A brilliant hat-trick from Nenê and a magnificent performance from Jérémy Ménez handed Paris Saint-Germain a win against Rennes that keeps them in the title running with a game to spare.
[56] Lyon inflicted a first defeat of the Ancelotti era on PSG and reached the last four of the French Cup, where they joined Gazélec Ajaccio, who stunned Montpellier, and Rennes, winners over Valenciennes.
[59] Big-spending Paris Saint-Germain had to face Greek outfit Olympiakos Volou in the UEFA Europa League play-offs over two legs for a place in the group stages.
[60] Olympiakos Volou, however, were excluded from the Europa League for their involvement in a match-fixing scandal, with UEFA handing the Greek club a three-season ban from continental competition.
[63] Javier Pastore provided two assists in his debut to help Paris Saint-Germain take a commanding lead into the second leg of their UEFA Europa League play-off tie against Differdange.
[64] Paris Saint-Germain never looked in danger of squandering their first-leg lead as they claimed a convincing win over Differdange to take the tie 6-0 on aggregate and advance to the group stages.
[65] Paris Saint-Germain were top seeds for the draw in Monaco and were placed in a testing Group F alongside Athletic Bilbao, Slovan Bratislava and Red Bull Salzburg.
[69] Javier Pastore's lone strike was enough to secure Paris Saint-Germain a narrow win over a tenacious Slovan Bratislava side at the Parc des Princes and reassert the capital club's claim on a qualifying spot for the knockout rounds of the Europa League.