In addition to the domestic league, Metalist Kharkiv participated in that season's editions of the Ukrainian Cup and the UEFA Europa League.

The season covers the period from 1 July 2012 to 30 June 2013.

Note: Flags indicate national team as defined under FIFA eligibility rules; some limited exceptions apply.

Players may hold more than one non-FIFA nationality.

Note: Flags indicate national team as defined under FIFA eligibility rules; some limited exceptions apply.