[4] On 24 April 2013 the FFU Executive Committee changed location of the final match from Olimpiysky in Kyiv to Metalist in Kharkiv.

[5] In this round entered 16 clubs from the Druha Liha and the finalists of Ukrainian Amateur Cup.

[8] ^(4) Hvardiyets Hvardiyske were drawn to play away against FC Bastion Illichivsk but they were omitted from the professional ranks prior to the start of the 2012–13 season.

[6] ^(6) Stal Dniprodzerzhynsk were originally drawn to play away against FC Lviv but they withdrew from the professional ranks prior to the start of the 2012–13 season.

The draw took place 5 September 2012[11] and was performed by Volodymyr Troshkin who was invited as a guest by the Premier League.

[11] ^(7) Fixture played at the CSC Nika Stadium located in the district center of Oleksandria, since the home ground has limited capacity.

The draw took place September 26, 2012[13] and was performed by Mykhailo Fomenko who was invited as a guest by the Premier League.

[13] ^(8) Fixture played at the CSC Nika Stadium located in the district center of Oleksandria, since the home ground has limited capacity.