In addition to the domestic league, Villarreal participated in this season's edition of the Copa del Rey.

The season covered the period from 1 July 2012 to 30 June 2013.

Win Draw Loss Postponed Source: Competitions Source: [citation needed] The numbers are established according to the official website:[1] and www.lfp.es Note: Flags indicate national team as defined under FIFA eligibility rules; some limited exceptions apply.

Players may hold more than one non-FIFA nationality.

Note: Flags indicate national team as defined under FIFA eligibility rules; some limited exceptions apply.