In the final, Benfica defeated Rio Ave 1–0, courtesy of a first-half goal by Nicolás Gaitán, and won the competition for a record 25th time.
As the winners of the Taça de Portugal, Benfica earned the right to play in the 2014–15 UEFA Europa League group stage.
However, since they had already qualified for the 2014–15 UEFA Champions League as the 2013–14 Primeira Liga winners, Rio Ave took their place as the cup runners-up.
In addition, Benfica qualified for the 2014 Supertaça Cândido de Oliveira, where they faced again Rio Ave, as a result of having won both league and cup titles.
As in the previous season, the competition format was organized in a knockout system consisting of seven rounds preceding the final match.
A total of 156 teams competing in the top four tiers of the Portuguese football were considered eligible by FPF to participate in the competition: