The season featured 17 teams from the 2012–13 Azadegan League, four new teams relegated from the 2012–13 Persian Gulf Cup (Aluminium Hormozgan, Sanat Naft, Paykan and Gahar Zagros) and four new teams promoted from the 2012–13 2nd Division (Naft va Gaz Gachsaran and Siah Jamegan both as champions and Sanaye Giti Pasand and Albadr Bandar Kong).
Padideh replaced Mes Sarcheshmeh.
The league started on 22 September 2013 and ended on 8 April 2014.
Padideh won the Azadegan League title for the first time in their history.
Padideh, Naft Masjed Soleyman and Paykan won promotion to the Persian Gulf Pro League.