[3] Rodríguez won the general classification by four seconds over runner-up and compatriot Alberto Contador (Tinkoff–Saxo),[4] while the BMC Racing Team's Tejay van Garderen completed the podium, three seconds behind Contador,[5] and seven down on Rodríguez; van Garderen was the winner of the race's queen stage to Vallter 2000-Setcases on the fourth day.

[6] In the race's other classifications, Stef Clement, of the Belkin Pro Cycling team,[5] was the winner of the red jersey for the mountains classification; he also won a stage wearing the jersey, winning on the penultimate stage.

The 22 teams that competed in the race were:[10] In the 2014 Volta a Catalunya, four different jerseys were awarded.

For the general classification, calculated by adding each cyclist's finishing times on each stage, and allowing time bonuses in intermediate sprints and at the finish in mass-start stages, the leader received a white and green jersey.

A special sprints classification was also contested, with points on offer at a specific point during the stage; the classification was named in honour of former cyclist Miguel Poblet, who died in 2013.