The 2016 season of Clube Recreativo e Desportivo do Libolo was the club's 11th season in Angolan football, and the 9th consecutive season in the Girabola, the top flight of Angolan football.

In 2016, the club participated in the Angola Super Cup, Girabola, Angola Cup and the CAF Champions League.

[1] Assistant referees: Bernabé Ngulo Judith Mestre Fourth official: Mauro de Oliveira [2] Last updated: 5 Nov 2016.

Source: [1][usurped] [3] [4] Assistant referees: Júlio Lemos Joaquim da Rocha Last updated: 5 Nov 2016.

Source: [2][usurped] Appearances denote players in the starting lineup, with the numbers in parentheses denoting appearances as substitute.