In addition to the domestic league, Valencia participated in this season's edition of the Copa del Rey, finishing as runners-up.

Note 1: Javier Jiménez moved back to Albacete after his loan ended on a permanent deal.

Note 2: Adrià Guerrero joined Zürich after returning to the club on a permanent deal.

Note 1: Jorget Saenz's loan at Portuguese club Marítimo was cancelled mid-season before he moved to Mirandés.

[41] Win Draw Loss Fixtures Source: Soccerway Source: La Liga The league fixtures were announced on 30 June 2021.