The 2022–23 season was the 102nd season in the existence of Deportivo Alavés.

Alavés played in the Segunda División, the second division of men's professional football in Spain, after being relegated from the Spanish first division La Liga the previous season, finishing in last place.

Deals officialized beforehand were effective starting 1 July 2022.

Deals officialized beforehand will be effective starting 1 January 2023.

Win Draw Loss Fixtures Source: FBREF Notes Source: LaLiga SmartBank Asier Villalibre 46' Toni Maya  73' Antonio Blanco  82' Julián Delmás  39' Luis Muñoz  69' Carlos Benavídez  42' Rubén Duarte  60' Luis Rioja  90+1' Gustavo Blanco Leschuk  40' Juan Diego Molina Martínez 45+1' Javier Muñoz  48' Anaitz Arbilla  60' Abdel Abqar  65' José Luis García Vayá  97' Roberto Soldado  105+5' Vicente Iborra  105+5' Joaquín Panichelli  100' Abdel Abqar  112' Carlos Benavídez  114' Antonio Sivera  120+3'