Women season was the club's 34th season of competitive football and first season back in the Women's Super League, the highest level of the football pyramid, since their relegation at the end of the 2019–20 season.

Note: Flags indicate national team as defined under FIFA eligibility rules; some limited exceptions apply.

Players may hold more than one non-FIFA nationality.

Source: FA WSL As a member of the first tier, Liverpool entered the FA Cup in the fourth round proper.

Ranking of second-placed teams