The winners of each group of 2023-24 season in Primera Catalana and the best team in 2023-24 Lliga Elit which not achieved promotion, UE Vic, entered the competition in this round.
[9] All sixteen non-reserve teams which played in the Catalan group of 2023-24 Tercera Federación entered the competition in this round, including former champions CE L'Hospitalet.
[11] All six non-reserve Catalan teams which played in the 2023-24 Segunda Federación entered the competition in this round, including former champions CE Europa, UE Sant Andreu and Terrassa FC.
All 3 non-reserve Catalan teams which played in the 2023–24 Primera Federación entered the competition in this round, including Club Gimnàstic de Tarragona, CE Sabadell FC and UE Cornellà.
Both Catalan teams which played in the 2023–24 Segunda División entered the competition in this round, including FC Andorra and RCD Espanyol.