Alunogen

Alunogen (from French alun, "alum"), also called feather alum and hair salt is a colourless to white (although often coloured by impurities, such as iron substituting for aluminium) fibrous to needle-like aluminium sulfate mineral.

[2][3] It is often found on the walls of mines and quarries as a secondary mineral.

It can be found in the oxidation zones of some ore deposits as well as on burning coal dumps (i.e., as the product of millosevichite hydration).

[2] It occurs associated with pyrite, marcasite, halotrichite, pickeringite, epsomite, potash alum, melanterite and gypsum.

The second formula shows that H2O in the alunogen formula occurs both as ligand (coordinative form) and loosely bound (crystallization) form.