In Paris at the time of the trial of Louis XVI, Antoine Philippe attempted unsuccessfully to persuade his father not to vote for the king's death.
In April 1793, whilst adjutant-general in the armée du Var, Antoine Philippe was arrested at the same time as the other Bourbons who had remained in France.
He set out on 5 November 1796, accompanied by his brother Louis-Charles, comte de Beaujolais, and in February 1797 met Louis-Philippe in Philadelphia.
Later that year Antoine- Philippe sought the hand in marriage of Lady Charlotte Adelaide Constantia Rawdon (d. 1834), daughter of the 1st Earl of Moira by his third wife, Elizabeth Hastings, 16th Baroness Botreaux (daughter of the 9th Earl of Huntingdon by his wife, Lady Selena Shirley, founder of the Countess of Huntingdon's Connexion).
Monsieur (the future King Charles X) attended and, thanks to Prince Edward, Duke of Kent, obtained permission to bury his brother in Westminster Abbey.