The programme was fronted by Huw Edwards, who at the time was the BBC's lead presenter for major breaking news.

The show included a detailed look at the news, as well as analysis with guests and sport and weather updates.

On 4 November 2013, the BBC News at Five received new opening titles featuring the broadcast hour.

George Alagiah presented from L'Aquila in April 2009 and Haiti in January 2010 when earthquakes struck the countries.

The Film Review appeared during the programme on Fridays between 5:45 pm and 6:00 pm, and is presented by, usually, Gavin Esler or Jane Hill and a film critic, usually Mark Kermode, from the main desk, however the background and lighting changes to resemble a cinema effect.