[4] The inaugural match was played between the hosts, Celta Vigo, and the Basque team Real Unión.

The ceremonial kick-off was made by Carmen Gregorio-Espino, the daughter of former mayor Adolfo Gregorio Espino.

After finishing in fourth place in the 2002–03 La Liga season,[5] Celta qualified for the UEFA Champions League for the first time in their history.

[6] It was briefly rumoured that Celta might have to play their home games at a different venue; however, the necessary upgrades were paid for by the local authorities.

[11] On 29 July 1990, as part of her Blond Ambition World Tour, Madonna performed at the stadium with Siniestro Total as the opening act in front of 20,000 people.

King, Celia Cruz, Dr. John, Gilberto Gil, Milton Nascimento, Tito Puente, Tracy Chapman and Willy Deville.

[citation needed] On 4 July 1998, A Roda, Astarot, Milladoiro and Carlos Santana performed in front of 12,000 spectators as part of Celta's 75th anniversary.