Bolivia has yet to win an Olympic medal, a distinction shared with no other South American nation.

Their best result at team event placing was in Athletics at the twenty-fifth edition of the Summer Olympics (1992).

The best result of individual event placing was in Athletics at the thirty-first edition of the Summer Olympics (2016).

In the Women's 20km Walk, Ángela Castro finished at eighteenth place out of seventy-four athletes.

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