Under such conditions, a large fraction of bosons occupy the lowest quantum state, at which microscopic quantum-mechanical phenomena, particularly wavefunction interference, become apparent macroscopically.
Bose–Einstein condensate was first predicted, generally, in 1924–1925 by Albert Einstein,[2] crediting a pioneering paper by Satyendra Nath Bose on the new field now known as quantum statistics.
Einstein proposed that cooling bosonic atoms to a very low temperature would cause them to fall (or "condense") into the lowest accessible quantum state, resulting in a new form of matter.
[13][14] On 5 June 1995, the first gaseous condensate was produced by Eric Cornell and Carl Wieman at the University of Colorado at Boulder NIST–JILA lab, in a gas of rubidium atoms cooled to 170 nanokelvins (nK).
[17] BEC of plasmonic quasiparticles (plasmon-exciton polaritons) has been realized in periodic arrays of metal nanoparticles overlaid with dye molecules,[18] exhibiting ultrafast sub-picosecond dynamics[19] and long-range correlations.
[20] This transition to BEC occurs below a critical temperature, which for a uniform three-dimensional gas consisting of non-interacting particles with no apparent internal degrees of freedom is given by where: Interactions shift the value, and the corrections can be calculated by mean-field theory.
In 1938, Pyotr Kapitsa, John Allen and Don Misener discovered that helium-4 became a new kind of fluid, now known as a superfluid, at temperatures less than 2.17 K (the lambda point).
Superfluid helium has many unusual properties, including zero viscosity (the ability to flow without dissipating energy) and the existence of quantized vortices.
Superfluid helium-4 is a liquid rather than a gas, which means that the interactions between the atoms are relatively strong; the original theory of Bose–Einstein condensation must be heavily modified in order to describe it.
[24] A group led by Randall Hulet at Rice University announced a condensate of lithium atoms only one month following the JILA work.
The peak is not infinitely narrow because of the Heisenberg uncertainty principle: spatially confined atoms have a minimum width velocity distribution.
Although initially just a proof of function, early results showed that, in the microgravity environment of the ISS, about half of the atoms formed into a magnetically insensitive halo-like cloud around the main body of the BEC.
Nikolay Bogoliubov considered perturbations on the limit of dilute gas,[35] finding a finite pressure at zero temperature and positive chemical potential.
By construction, the GPE uses the following simplifications: it assumes that interactions between condensate particles are of the contact two-body type and also neglects anomalous contributions to self-energy.
[49] Vortices can be created, for example, by "stirring" the condensate with lasers,[50] rotating the confining trap,[51] or by rapid cooling across the phase transition.
[55] Experiments led by Randall Hulet at Rice University from 1995 through 2000 showed that lithium condensates with attractive interactions could stably exist up to a critical atom number.
Quench cooling the gas, they observed the condensate to grow, then subsequently collapse as the attraction overwhelmed the zero-point energy of the confining potential, in a burst reminiscent of a supernova, with an explosion preceded by an implosion.
Through Feshbach resonance involving a sweep of the magnetic field causing spin flip collisions, they lowered the characteristic, discrete energies at which rubidium bonds, making their Rb-85 atoms repulsive and creating a stable condensate.
When the JILA team raised the magnetic field strength further, the condensate suddenly reverted to attraction, imploded and shrank beyond detection, then exploded, expelling about two-thirds of its 10,000 atoms.
Most likely they formed molecules of two rubidium atoms;[56] energy gained by this bond imparts velocity sufficient to leave the trap without being detected.
[58] The slightest interaction with the external environment can be enough to warm them past the condensation threshold, eliminating their interesting properties and forming a normal gas.
[59] Nevertheless, they have proven useful in exploring a wide range of questions in fundamental physics, and the years since the initial discoveries by the JILA and MIT groups have seen an increase in experimental and theoretical activity.
[62] Vortices in Bose–Einstein condensates are also currently the subject of analogue gravity research, studying the possibility of modeling black holes and their related phenomena in such environments in the laboratory.
Indeed, a deep optical lattice allows the experimentalist to freeze the motion of the particles along one or two directions, effectively eliminating one or two dimension from the system.
[69] In 1999, Danish physicist Lene Hau led a team from Harvard University which slowed a beam of light to about 17 meters per second[clarification needed] using a superfluid.
[71] Another current research interest is the creation of Bose–Einstein condensates in microgravity in order to use its properties for high precision atom interferometry.
The first demonstration of a BEC in weightlessness was achieved in 2008 at a drop tower in Bremen, Germany by a consortium of researchers led by Ernst M. Rasel from Leibniz University Hannover.
[78] Bose-Einstein condensation has mainly been observed on alkaline atoms, some of which have collisional properties particularly suitable for evaporative cooling in traps, and which where the first to laser-cooled.
However the important search for them has been greatly enhanced with the completion of upgrades to the Axion Dark Matter Experiment (ADMX) at the University of Washington in early 2018.
[94] It is theorized that groups of d* (d-stars) could form Bose–Einstein condensates due to prevailing low temperatures in the early universe, and that BECs made of such hexaquarks with trapped electrons could behave like dark matter.