[10] As a model, she has appeared on the covers of Ocean Drive,[11] the Brazilian edition of Men's Vogue,[12] ES Magazine, Maxim, Town & Country, People[13] and Bella.

[14] She has walked the runway at fashion shows for Valentino,[15] Carolina Herrera,[15] Mango, The Heart Truth's Red Dress Collection[16] and TCN.

[21] In January 2016, Alves launched a lifestyle website, Women of Today, that serves as a hub for her social media; livestream video program, Camila's Code; and blog posts on food, health, crafts & décor, style, family, and work life.

[23] She co-hosted, with Eddie Jackson, the first season of the Food Network competition show Kids BBQ Championship, which aired in summer 2016.

[26] The couple became engaged on Christmas Day in 2011[27] and were married in a private Catholic wedding ceremony on June 13, 2012, in Austin, Texas, where they reside.