On April 13, 2012, Bustamante signed with the Tigres de Quintana Roo of the Mexican League.
For the 2015 season, Bustamante pitched in 24 games for Quintana Roo, logging a 2–2 record and 2.84 ERA with 50 strikeouts in 66+2⁄3 innings of work.
On June 21, 2017, Bustamante signed a minor league contract with the Arizona Diamondbacks organization.
[3] He split the year between the AZL Diamondbacks, the rookie-level Missoula Osprey, and the Single-A Kane County Cougars, posting a cumulative 0.31 ERA in 17 appearances.
In 47 games for Monclova, he registered a 2.57 ERA with 27 saves and 67 strikeouts, and earned Mexican League All-Star honors.