The Korean version of "Catch Me" was made available for download on September 24, 2012, the same date as the full album's digital release.

[2] A mix of house and dubstep, "Catch Me" was met with acclaim, with critics praising the back track's orchestral riffs and the duo's vocal harmony.

[4] Selling over 137,000 copies on its first week of release, "Catch Me" was certified gold by the Recording Industry Association of Japan (RIAJ) for shipments of over 100,000.

[5] Written and produced by Yoo Young-jin, "Catch Me" is an electropop song with orchestral melodies, dubstep sounds, house beats, and powerful vocal belting.

[11] The Japanese released was more well-received, debuting at number-one on Oricon's Daily Singles Charts, selling 84,666 copies.

[12] It maintained its number one position the following day and sold an additional 25,349 copies, bringing its total sales to 110,015.

[15] Critics described the song as "nostalgic", as the duo's vocal high-note belting performances are highly evocative of their older music.

[16][17] Writing for Fuse, Jeff Benjamin noted the song's choreography with "craft gravity-defying leans, quick jumps from ground to floor and splash through a water-infused video set."

[3] In the choreography, Testa used the back-up dancers in a way that could show members U-Know Yunho and Max Changmin doing "superhuman" moves, such as extended arms and waves.

Yunho says "catch me if you wanna" and its electronic music picks up, inter cuts with shots of TVXQ dancing in water and mirrored sets.