Centerville is a borough in Washington County, Pennsylvania, United States.

Across the Monongahela River in Fayette County to the south, Centerville runs adjacent with Brownsville and Luzerne Township.

As of the census[7] of 2010, there were 3,263 people, 1,359 households, and 971 families living in the borough.

There were 1,455 housing units at an average density of 109.8 per square mile (42.4/km2).

26.4% of all households were made up of individuals, and 16.1% had someone living alone who was 65 years of age or older.