Gosselin débuted at the Opéra de Paris in 1810, after studying dance under Louis Duport and Jean-François Coulon.

Her dance style was elegant and discrete, predisposing her to serious roles in ballets by Pierre Gardel, Jean-Pierre Aumer and Albert.

Following Madame Anatole's three-month leave in London in January 1822, where her husband served as ballet master at the King's Theatre, the Académie Royale de Musique and the King's Theatre entered into an agreement to avoid hiring each other's dancers.

She was the daughter of a dancing master and younger sister of the French ballet dancer Geneviève Gosselin.

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