Darbyville is a village in Pickaway County, Ohio, United States.

There were 92 housing units at an average density of 195.7 per square mile (75.6/km2).

The racial makeup of the village was 98.2% White, 0.5% African American, and 1.4% from two or more races.

22.8% of all households were made up of individuals, and 12.7% had someone living alone who was 65 years of age or older.

17.0% of all households were made up of individuals, and 7.4% had someone living alone who was 65 years of age or older.

About 18.3% of families and 22.0% of the population were below the poverty line, including 25.9% of those under the age of eighteen and 25.0% of those 65 or over.