Born in Dapaong, Djené moved to Benin in 2009, after graduating from Étoile Filante du Togo's youth setup, joining Tonnerre d'Abomey.
[6] In August 2014, Djené went on a trial at Spanish Segunda División side AD Alcorcón,[7] joining the club permanently on 25 October.
[11] On 24 July of the following year, he returned to Spain, after agreeing to a four-year deal with La Liga side Getafe CF.
Djené was named in Togo's main squad for the 2011 WAFU Nations Cup, shortly after being called up by Benin.
[14] Djené was included in Didier Six's 23-man squad for the 2013 Africa Cup of Nations,[15] and appeared in all of Togo's matches during the tournament, being eventually knocked out in the quarter-finals.