Zharoff is married and lives in Tucson, Arizona[3] with her husband, Kirk McCune, and their son, Mycroft.

After initial engagements at the Opera Philadelphia, Zharoff was a member of the Young Ensemble of the Dresden Semperoper in the 2012/13 season, where she sang Pamina in Mozart's Magic Flute and Violetta in Verdi's La traviata.

In addition to embodying other soprano roles at various opera houses, she appeared on the concert stage with the Cleveland Orchestra and performed a chamber piece composed for her by Richard Danielpour.

In the 2013/14 season she made her debut as Giunia in Lucio Silla at the Opéra National de Bordeaux.

Even if the voice in the forte sounded rather harsh, the height was occasionally a nuance too low and a superficially (visible and) audible vibrato somewhat diminished the overall impression in the close-up, over the course of the performance she showed stamina and concentration and was touching her beautiful soulful piano passages.

At the suggestion of her subscribers, she began to devote her analysis to rock and metal singers, whom she had never heard, such as Ronnie James Dio and Rob Halford and, increasingly, to extreme, guttural vocals, featuring subgenres such as deathcore.

She used a Kickstarter campaign in September, 2024 to create The Charismatic Voice Research Fund which will allow university studies of this largely understood function, using professional singers as test subjects.