Her father, Manuel González was a farmer and her mother, Encarnación Fernández was a housewife.

From 2004 to 2005, González was in a relationship with the actor, comedian and television presenter Arturo Valls.

From 2005 to 2008, González was in a relationship with the retired professional football player Iker Casillas.

On 6 November 2015, she married the bullfighter, Cayetano Rivera Ordóñez in the Church of Nuestra Señora de la Asunción of Mairena del Alcor in Seville.

On 4 March 2018, she gave birth to the couple's first child, a boy, whom they called Cayetano Rivera González, was born in Seville.