[2] At the 2004 Summer Olympics, Psarra entered the women's competition as Greece's best hope for a medal having finished eighteenth overall at the 2003 World Archery Championships.
[6] Psarra narrowly missed qualifying for the 2016 Summer Olympics at the Final Qualification Tournament in Antalya in June 2016, which allocated the remaining six positions available for the women's individual event.
[7] The withdrawal of an archer from Côte d'Ivoire in July however led to a vacant position, which was assigned to Greece as the highest ranked nation without an Olympic berth.
[8] Psarra entered Rio de Janeiro as the most experienced Olympian in the field, finishing the ranking round in fifty-fifth place.
She was eliminated in the first round for her third Olympic Games in a row, losing to Japan's Kaori Kawanaka by seven set points to three.