A native of Nueva Ecija, she was born (second to three siblings) to Araceli Harding (née Dionisio) and Pedro Molina with the former who later became estranged from the latter and married to an India-based to British engineering consultant.

She was supposed to join the Philippine women's national volleyball team that will participate in the 1991 Southeast Asian Games, but it was discontinued due to earlier marriage, and her work in a company based in Macau.

[1] Molina grew up in the town of Aliaga and moved to Cabanatuan to attend the Araullo University (later transferred to College of Immaculate Conception)[1] for her secondary studies.

[4] In 2017, she became part of the Philippines women's national volleyball team that competed in various tournaments like ASEAN Grand Prix and 2019 SEA Games.

In 2021, Molina signed to Petro Gazz Angels to play in the first season of Premier Volleyball League on its professional status.