Born in Súria, Province of Barcelona, Spain, Molina alongside his family moved to Chile when he was nine in 1939.

[2] They settled at Valparaíso after arriving there on board of SS Winnipeg as one of the 2.200 exiles which escaped from the Spanish Civil War.

[3] During 1940s Molina joined Santiago Wanderers youth set-up with prior spell playing at amateur club Deportivo Roberto Parra.

[4] Molina made his international debut in a friendly match versus Yugoslav club Hajduk on 18 February 1953, where he scored a goal and Chile won 4–1.

Next, he coached several clubs at the Chilean Primera División, including Colo-Colo.[4] Audax Italiano Universidad Católica Individual