Born in Nikolsburg, he was the third child and second (but eldest surviving) son of Karl Johann Baptist, 7th Prince of Dietrichstein, and Countess Maria Christina Josepha of Thun und Hohenstein (1738-1788), eldest daughter of Count Jan Josef Franz Anton of Thun-Hohenstein (1711-1778) and his wife, Countess Maria Christiana of Hohenzollern-Hechingen (1715-1749).
He was educated at Nikolsburg Castle by provost Jean du Four, an en-lightener and friend of his mother, who gave Franz Joseph an open mind and heart.
[1] Franz Joseph inherited the title of Prince of Dietrichstein after his father's death on 25 May 1808; as the owner of the wealthy Fideikommiss who belonged to his family after the death of Prince Gundacar (from the Hollenburg line) in 1690 and his own family domains (from the Nikolsburg branch), he also entered in the possession of the hereditary Erbamt, who allowed him to took place in official court ceremonies, like royal and imperial coronations.
In 1809 he was appointed as Obersthofmeister of Archduke Francis Joseph Charles of Austria, later Duke of Modena, and in this function he acted as Hofkommissar in the enemy-occupied part of Galicia until the Congress of Vienna.
The prince led an unconventional, free lifestyle and sired several illegitimate children, including the famous pianist Sigismund Thalberg.