The song was written by Twain, with additional production and songwriting by Robert John "Mutt" Lange.

"From This Moment On" is a country pop track that received generally favourable reviews from music critics, who deemed the song as one of the highlights on the album.

According to White's spokesman at Asylum Records, "We've certainly heard knocking on our door about "From This Moment On" being too contemporary for Bryan's sake; therefore, it is fine if they want to go to the Top 40 without him."

[1][5][6][7] Musically, "From This Moment On" is a country pop ballad set in common time with a free tempo.

[9] Nick Reynolds of BBC Music described the song as a power new country ballad with "a beautiful melody".

Pan-European magazine Music & Media wrote that Twain sounded "something like a cross between the Corrs and Celine Dion".

While reviewing the duet, Coyne graded it a B and commented that it was mostly a showcase of White's vocals, "who turns in some signature licks and makes Twain seem a bit bland in comparison.

"[13] Coyne concluded, however, that the single release turned the track "into a potent solo number," and noted that "the addition of a Spanish-flavored guitar that borrowed heavily from 'Have You Ever Really Loved a Woman' gave the ballad added oomph."

[18] The song failed to chart inside the top 10 of a few European countries, such as France, Netherlands, and Sweden.

[19] In the United Kingdom, the song debuted and peaked at number nine on the chart issue of November 18, 1998,[20] and has sold more than 295,000 copies in the nation as of June 2019.

This re-recorded solo version features slightly more contemporized instrumentation and removes White's vocals.

"Da Stanotte in Poi (From This Moment On)" is a song recorded by Italian tenor Andrea Bocelli and Shania Twain.

It was released on 12 July 2024 through Decca Records as the lead single from Bocelli's fourth compilation album Duets (30th Anniversary).

[66] On July 19, 2024, the artists performed the song during the final date of Andrea Bocelli 30: The Celebration at the Teatro del Silenzio in Tuscany.