[8] Having started as a defensive midfielder, Rutgers moved her to the center back role in her junior year.
[9] During her time at Rutgers, Provenzano was nicknamed "The General" by manager O'Neill, who also named her as team captain.
[9][17] On March 15, 2022, Thorns FC announced that the club had signed Provenzano to a one-year contract, with an option for an additional year.
[18] On March 5, 2022, Provenzano made her professional debut for Thorns FC in a 0–0 preseason draw against OL Reign.
[20] Having collected four appearances throughout the 2022 season, she gained her first professional title as Thorns FC won the NWSL Playoffs over Kansas City Current.