Coldplay vocalist Chris Martin said, about the writing of the song, "That came out of playing live and wanting to have something with a bit more bounce.
"[3] When asked about the development of the song, during a track-by-track reveal, bassist Guy Berryman said: When we came to record it in the studio we struggled because there was something just not quite right about it and I wasn't happy about where we'd left it and where we were happy to leave it and we couldn't put our finger on what it was and so it was a really nice day one day, me and Chris were just trying, I was actually just trying to record bass at the time and me and Chris were just sitting down trying to brainstorm it and work out what was wrong and so I started trying to just do a few different bass lines and stuff.
The song starts with a hushed acoustic ballad before building into a roar of an electric guitar and soaring with vocals.
In the Rolling Stone review of the album, critic Rob Sheffield wrote: "'God Put a Smile Upon Your Face' is the slinkiest and best thing Coldplay have ever done.
"[17] Adrien Begrand of PopMatters wrote: "Buckland's lead fills highlight the wondrous 'God Put a Smile on Your Face', as the song's chorus reaches heights that rival those of their fellow countrymen Doves.
"[18] Ted Kessler of NME wrote: "Over a pounding garage tattoo Martin poses a deep, mortality-based teaser ('where do we go from here?
[21] The American TV series Alias used the song in the second-season episode "Double Agent", which originally aired on 2 February 2003.
[15][27] The video intercuts footage of the band performing the song with the story of a businessman (played by actor Paddy Considine), who is walking when he bumps into a mysterious suited but barefoot stranger.
As the businessman continues walking, he drops his briefcase, and when he attempts to pick it up, he is shocked when his hand goes through the handle, turning invisible.