A special edition of the record was also released and features six extra songs as well as a DVD containing music videos from Miguel's career.

Grandes Éxitos received a favorable review by AllMusic critic, Thom Jurek who commended Miguel's trajectory as an artist.

[2][4] "Misterios del Amor" was released as the album's lead single on 24 October 2005 and peaked at number 29 on the Billboard Hot Latin Songs chart in the United States.

[5][6] "Si Te Perdiera" was released as the album's second single on 16 January 2006 and peaked at number 47 on the Hot Latin Songs chart.

[8] AllMusic critic Thom Jurek gave Grandes Éxitos four-out-of-five stars noting Miguel's maturity from a teen idol into crooner.