After a short junior career, Naw began to play ITF events in both the singles and doubles draw.

In August 2021, he received a wildcard into the doubles draw of the Platzmann-Sauerland Open, a Challenger event in Germany which he played alongside former top-100 player Dustin Brown.

[citation needed] Naw made history as the first Syrian tennis player to record a win in a singles Challenger main draw with his victory over Billy Harris at the 2024 Koblenz Open, having qualified for the main draw.

[3][4] Naw is the younger brother of fellow tennis player Amer Naow.

Due to the Syrian Civil War, Naw was forced out of Aleppo and moved to Beirut, Lebanon,[5] but now plays tennis for local leagues in Germany.