The single was produced and written by Rich Harrison, who has additionally worked with Beyoncé on her chart-topping 2003 hit "Crazy in Love" and Amerie on "1 Thing".

Many critics have given positive reviews on the single, complimenting Harrison's beat as "hectic" and "blinding" and being in huge favor of the ladies' vocal-performances, stating that when both are added together it creates a song as "dangerous" as "He Ain't wit Me Now (Tho)."

Daniel of MTV Buzzworthy stated "I do expect that this jam is gonna bounce your ass all the way through summer before you even notice school's out.

[9] With a rating of seven out of ten, NewMusicReviews named the single decent, stating that although it might not find multiple chart-success it may still receive plenty of "action.

[13] "He Ain't wit Me Now (Tho)" has been paced at mid-tempo, seeing production duties by Rich Harrison, who has additionally worked with Beyoncé on her chart-topping "Crazy in Love" and Amerie on "1 Thing".

[14] Instrumentally, the song features Harrison creating a blinding beat, built around a loop of mid-century Hungarian classical music, that has been described as being "inspired by absurdist literature".

Seven and Audra pose in a white square frame that is standing up, and Brave sings her verse on top of a box that is being spun around by men as she keeps her face towards the camera.

Daniel of MTV Buzzworthy gave the video a very positive review stating "This 'He Ain't Wit You Now (Tho)' clip is so off-the-charts summer stanknasty, we gotta do it backwards and roll it right now.

"[8] Daniel additionally complimented the girls by comparing their choreography to that of Michael Jackson and stating that they "create serious heat" once their vocals are added into the mix.