He is a descendant of the royalist military leader François de Charette and of king Charles X of France.
Member of the Union for French Democracy (UDF), he was elected deputy for the first time in 1986 as representative of the Maine-et-Loire département.
Like him, and contrary to the most part of the UDF politicians, he supported the winning candidacy of Jacques Chirac in the 1995 presidential election and not that of Prime Minister Édouard Balladur.
In this, after the campaign, he found and led the Popular Party for French Democracy (PPDF), a component of the UDF, and served as Minister of Foreign Affairs until the defeat of the Presidential Majority in the 1997 legislative election.
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