[3] Goulart once said, "the hardest part about being [a Victoria's Secret Angel] is I spend time away from my mom's food and away from my home with my five siblings".

[4] School was a particularly rough time for Goulart, as she was made fun of for her skinny build and was called names such as "giraffe".

She eventually put this event behind her and returned to the runway to model collections for A-list designers such as Alberta Ferretti, Bill Blass, Balenciaga, Bottega Veneta, Isabel Marant, Givenchy, Altuzarra, Oscar de la Renta, Valentino, Balmain, Jil Sander, Chanel, Michael Kors, Ralph Lauren, Emilio Pucci, Dolce and Gabbana, Emanuel Ungaro, Loewe, Roberto Cavalli and Stella McCartney, among others.

In 2005, Goulart appeared on the covers of the April edition of Marie Claire France and, in December, Vogue Brazil.

In 2008, she replaced fellow Victoria's Secret Angel Alessandra Ambrosio as the face of A/X Armani Exchange and she was featured in three seasonal print campaigns for the label.

In November, she was recognised as "Fashion Personality of the Year" by the Brazilian magazine Isto é Gente,[14] and she also appeared on the cover of Glamour Brazil in December 2012.

In February 2013 she appeared on the cover of one of the four issues of Vogue Brasil, together with Bette Franke, Magdalena Frackowiak, and Mirte Maas.

In mid-2013, she became the face of MAC Cosmetics Tropical Taboo range and she was photographed by Zee Nunes for the October edition of Vogue Brazil in an editorial entitled "Olympiada Fashion".