Pietersen was educated at the Hoërskool Generaal Hertzog in Witbank, but made his provincial debut with the Sharks as a 19-year-old during the 2005 Currie Cup season.
Upon arriving back to South Africa after the under-21 World Championship he was named in the Springboks' 2006 Tri Nations Series squad where he debuted against New Zealand at the Royal Bafokeng Stadium in Rustenburg.
Pietersen's deceptive pace and gliding runs make him an unpredictable back-line player, with the ability to break the line at will and create attacking opportunities for his team.
The top try-scorer in the 2007 Super 14 failed to score even one in 2008, a fact acknowledged by both AJ Venter and Stefan Terblanche in the October 2008 edition of SA Sports Illustrated.
However, post World Cup Pietersen went on to establish the most capped wing combination in Springbok history with Bryan Habana, standing currently at 25 tests, ten more than next best, James Small and Jaques Olivier.
His cover defence being the saving grace of the Springbok's 2008 End of Year Tour, manfully keeping the Welsh at bay, and dominating his opposite Shane Williams.