During the 2001 and 2002 seasons, Wynne was the number-two halfback behind Andrew Johns and was only able to secure five first-grade games.
In 2003, Wynne found himself a starting position with French club, Toulouse Olympique, where he was captain.
In June, 2007, Wynne was selected for France (qualifying through residency) against Great Britain where he started from the bench.
[2] James was named Man of the Match in the Rugby League World Cup win over Scotland in Canberra on Sunday 26 October 2008.
He is now a Fixed Plant Mechanical Supervisor for Newcrest Mining at Cadia Valley Operations 20 kilometres (12 mi) south of Orange NSW.