She moved to Los Angeles later that year and landed the recurring role of Helena Bertinelli/The Huntress in the action-adventure series, Arrow.
In 2013, De Gouw was cast in the NBC series Dracula as Mina Murray alongside Jonathan Rhys Meyers[2] and Oliver Jackson-Cohen.
In 2016, De Gouw was cast as fictional abolitionist Elizabeth Hawkes in the WGN series, Underground.
She played the lead role Ren Amari in the 2017 feature film OtherLife based on the novel Solitaire by Kelley Eskridge.
[8] De Gouw and her girlfriend, hairstylist Sophie Roberts, spoke about the pair's relationship for the February edition of Vogue in 2023.