[2] He graduated from Valdosta High School and then attended Mercer University where he was president of the Sigma Pi fraternity chapter and the Ciceronians debate and literature society.
[4][5] He married Jo Smith of Seminole County, Georgia on September 25, 1935, in Donalsonville.
At the local level, he was a men's Sunday School teacher for over forty-five years, and chairman of the Thomasville District Trustees and the Magnolia Manor retirement home board of trustees.
[4][5] Webb owned the Donalsonville News newspaper and the Seminole Drug Company for several years.
He was engaged in farming and was a member of the board of directors of Chattahoochee Industrial Railroad.
He served as president and deputy district governor for the Lions Club, and was director of the Chamber of Commerce.
[4] He was a delegate to the World Peace through Law Conference in Geneva, Switzerland, in 1967 and in Washington, D.C., in 1975.
He was also a member of the Masonic Lodge, the Royal Arch Masons, the Knights Templar, the Scottish Rite Temple, the Hasan Shrine Temple, and the Royal Order of Jesters.
[10] Webb eventually moved to St. Simon Island where he died a couple of months after his wife.