Burnette was appointed on October 29, 2013, by Pope Francis, and enthroned in a Divine Liturgy at the Cathedral of St. Michael the Archangel in Passaic, New Jersey on December 4.

[2] On 20 October 2020, Pope Francis named Burnette as apostolic administrator of the former Slovak Catholic Eparchy of Saints Cyril and Methodius of Toronto.

[3][4] On 3 March, 2022, Pope Francis changed the jurisdiction and circumscription of the eparchy to establish the Exarchate of Saints Cyril and Methodius of Toronto.

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