[2] Latvia qualified one athlete based on the 1 June 2014 Olympic Youth A Pentathlon World Rankings.

[3] Latvia was given a reallocation boat based on being a top ranked nation not yet qualified.

[4] Latvia qualified one shooter based on its performance at the 2014 European Shooting Championships.

[6] Latvia qualified one athlete based on the 9 June 2014 ITF World Junior Rankings.

[7] Latvia was given a reallocation spot to compete.