Li's performance during his time at the Chinese national team fluctuated wildly, due primarily to switching of tactics.

In 2006, the duo won a pair of gold medal in their category at the Asian Games held in Doha.

Li himself did not do as well in the solo table tennis discipline, being defeated by fellow Chinese athletes during the semi-final stages.

Li is now a table tennis coach and led the Hong Kong women's team to a bronze at the 2020 Summer Olympics.

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