In 2000, Li entered China women's national junior volleyball team.

In 2002, Li was called into China women's national volleyball team for the first time, along with her teammates in Tianjin Bridgestone, Li Shan, Zhang Ping and Zhang Na.

Li participated in the 2008 Beijing Olympics, as a member of China women's national volleyball team, and won the bronze medal.

[1] In the women volleyball final China vs. South Korea of 2010 Guangzhou Asian Games her final strike won the game for China.

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