She also co-starred in the 2007 CW sitcom Aliens in America, and was the lead on ABC Family's 2009 comedy series 10 Things I Hate About You.

From 2011 to 2017, she played the recurring role of Paige McCullers on the ABC Family teen drama series Pretty Little Liars.

Shaw portrayed Jennifer Ann "Moze" Mosely on the Nickelodeon series Ned's Declassified School Survival Guide, which debuted in 2004 and ended in 2007 after three seasons.

[10] She starred as Trip alongside Andy Serkis in Ninja Theory's videogame Enslaved: Odyssey to the West, released in October 2010.

[15] Shaw was in a relationship with her co-star Devon Werkheiser, during the last few months of filming Ned's Declassified School Survival Guide, and afterwards for over a year.