The liquefaction of gases is a complicated process that uses various compressions and expansions to achieve high pressures and very low temperatures, using, for example, turboexpanders.
Liquefaction is used for analyzing the fundamental properties of gas molecules (intermolecular forces), or for the storage of gases, for example: LPG, and in refrigeration and air conditioning.
Liquefied chlorine is transported for eventual solution in water, after which it is used for water purification, sanitation of industrial waste, sewage and swimming pools, bleaching of pulp and textiles and manufacture of carbon tetrachloride, glycol and numerous other organic compounds as well as phosgene gas.
Below 2.17 K liquid 4He becomes a superfluid (Nobel Prize 1978, Pyotr Kapitsa) and shows characteristic properties such as heat conduction through second sound, zero viscosity and the fountain effect among others.
With the lower temperature the molecules move more slowly and occupy less space, so the air changes phase to become liquid.