Lithium metaborate is one of the borates, a large family of salts (ionic compounds) with anions consisting of boron, oxygen, and hydrogen.
[2] Lithium metaborate forms glass relatively easily, and consists of approximately 40% tetrahedral borate anions, and 60% trigonal planar boron.
[3][4] Molten lithium metaborate, often mixed with lithium tetraborate Li2B4O7, is used to dissolve oxide samples for analysis by XRF, AAS, ICP-OES, ICP-AES, and ICP-MS,[5] modern versions of classical bead test.
The process may be used also to facilitate the dissolution of oxides in acids for wet analysis.
Most oxides are best dissolved in a mixture of the two lithium borate salts, for spectrochemical analysis.